The problem with flexible software is that it can get overly complicated. I certainly appreciate a good preset when they are offered.
Linear and Automatic exposure controls are not supported by Mental Ray. I'd suggest the mr Photographic EC. Are you using Final Gather by chance?
Although Mental Ray doesn't have quick check setting like in Revit, there are ways to up the quality. Under the Renderer tab you can adjust the minimum and maximum Samples per Pixel. The default is 1/4 min and 4 max. I'd start with 1 and 16. Any higher and you'll have some wicked render times.
HDR rules! If you are into PhotoMatrix, check out some of the photos on this link:
http://www.pbviz.com/forum/Topic1897-81-1.aspx
Pretty cool stuff. We use HDR quite readily as a secondary lighting source and reflections, both in override through V-Ray. You can achieve a similar look using the MR sky system. It's simple to set up and and some basic controls and adapts to the more "dramatic" morning or evening lighting. Initial setup is easy:
1) Create>Systems(the gear thingies)>Daylight>Click-n-drag
2) Environment Panel>Environment Map>open mr Physical Sky
Then it's tweaking the setting to get the result you want. I like to set the position on the light to "Manual" so I have more control with my scene.
Keep the questions coming! That's what we are here for..